Search results for "titanocene-EDOT derivative"

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Electrosynthesis and properties of poly(3,4-ethylenedioxythiophene) films functionalized with titanocene dichloride complex

2006

Synthesis of a titanocene dichloride derivative functionalized with 3,4-etylenedioxythiophene group, Tc1EDOT (Cl 2TiCpC5H4(CH2) (3,4ethylenedioxythiophene)) has been described. Redox behavior of the monomer in tetrahydrofuran (THF), dichloromethane (DCM) and acetonitrile (AN) at different scan rates has been discussed in terms of different ability of these solvents to coordination with the reduced titanocene (Tc) complex and the solvation of Cl − anions. Electrooxidation of Tc1EDOT to get a conducting polymer film with immobilized titanocene dichloride centers and electrochemical properties of its polymer matrix in background acetonitrile solution have been compared with those of non-substi…

Materials scienceGeneral Chemical EngineeringSTM02 engineering and technology010402 general chemistryElectrosynthesis01 natural scienceschemistry.chemical_compoundPEDOT:PSSPolymer chemistryElectrochemistryAcetonitrileComputingMilieux_MISCELLANEOUS[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph]poly(3Titanocene dichloride021001 nanoscience & nanotechnology0104 chemical sciences[ CHIM.POLY ] Chemical Sciences/Polymers[CHIM.POLY]Chemical Sciences/Polymers[ PHYS.PHYS.PHYS-AO-PH ] Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph]chemistryPolymerizationelectrodepositionimmobilized titanocene dichloride centersCyclic voltammetry4-ethylenedioxythiophene)0210 nano-technologyEDOT-methanol derivativeMetallocenePoly(34-ethylenedioxythiophene)titanocene-EDOT derivative

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